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.div1 {
	width:200px;
	height:200px;
	background:#f5f5f5;
	border:0px solid #666;
	position:relative;
}
.div1:after,.div1::before {
	content:"";
	width:0;
	height:0;
	border:2px solid transparent;
	display:inline-block;
	box-sizing:border-box;
	position:absolute;
}
.div1:after {
	top:0;
	left:0;
	transition:border-color 0s ease-in 2s,height 0.5s ease-in 1s,width 0.5s ease-in 1.5s;
}
/*必须拆解出来,这个是消失时候过渡*/
.div1:before {
	right:0;
	bottom:0;
	transition:border-color 0s ease-in 0.8s,height 0.5s ease-in,width 0.5s ease-in 0.5s;
}
/*必须拆解出来,这个是消失时候过渡*/
.div1:hover:after {
	border-top-color:#f60;
	border-right-color:#f60;
	height:100%;
	width:100%;
	/*transition:height 1s ease-out,width 1s ease-out 1s;
	*/ transition:width 0.2s ease-out,height 0.2s ease-out 0.2s;
}
.div1:hover:before {
	width:100%;
	height:100%;
	border-bottom-color:#367dff;
	border-left-color:#367dff;
	transition:width 0.2s ease-in 0.6s,height 0.2s ease-in 0.8s;
}

                        
↑上面代码改变,会自动显示代码结果 jQuery调用版本:1.11.3
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纯css3鼠标经过边框弹出

我是看到本站导航有这种效果,但是本站用的class名太多,一开始没搞懂要怎么做,后面经过自己摸索尝试中测试出来

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